Bis[μ-2,2′-dimethyl-1,1′-(3-oxapentane-1,5-diyl)di-1H-benzimidazole-κ2N3:N3′]bis[bis(4-methoxybenzoato)-κO;κ2O,O′-cobalt(II)]

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Bis[μ-2,2′-dimethyl-1,1′-(3-oxapentane-1,5-di­yl)di-1H-benzimidazole-κ2 N 3:N 3′]bis­[bis­(4-meth­oxy­benzoato)-κO;κ2 O,O′-cobalt(II)]

The complete mol-ecule of the title complex, [Co(2)(C(8)H(7)O(3))(4)(C(20)H(22)N(4)O)(2)], is a dimer of the paddle-wheel-type generated by crystallographic inversion symmetry. The Co(II) ion is penta-coordinated by three O atoms from two 4-meth-oxy-benzoate anions (one bidentate and one monodentate) and two N atoms from two 2,2'-bis-(2-methyl-1H-benzimidazole)-ether ligands. This results in a ...

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Dimethyl 2,2′-[2,2′-bi(1H-1,3-benzimidazole)-1,1′-di­yl]diacetate

The whole mol-ecule of the title compound, C(20)H(18)N(4)O(4), is generated by an inversion center. The benzimidazole ring mean plane make a dihedral angle of 89.4 (8)° with the plane passing through the acetate group (COO). In the crystal, mol-ecules are linked via weak C-H⋯O hydrogen bonds and π-π inter-actions [centroid-centroid distance = 3.743 (3) Å] involving inversion-related benzimidazo...

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(1H-Benzimidazole-5-carb­oxy­lic acid-κN 3)(1H-benzimidazole-6-carb­oxy­lic acid-κN 3)silver(I) perchlorate

The reaction of 1H-benzimidazole-5-carb-oxy-lic acid with silver nitrate in the presence of perchloric acid under hydro-thermal conditions yielded the title complex, [Ag(C(8)H(6)N(2)O(2))(2)]ClO(4), which comprises of an [Ag(C(8)H(6)N(2)O(2))(2)] mononuclear cation and a perchlorate anion. The Ag(I) ion is coordinated by two N atoms from two different neutral 1H-benzimidazole-5-carb-oxy-lic aci...

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3-Phenyl­diazen­yl-1,2-dimethyl-1H-indole

In the title mol-ecule, C(16)H(15)N(3), the indole ring system is planar within 0.021 (3) Å and the phenyl ring is inclined to this plane by 17.32 (14)°. π-π contacts involving the pyrrole rings of inversion-related indole units [centroid-centroid distance = 3.5187 (17) Å] stabilize the crystal structure.

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5,6-Dimethyl-1H-benzimidazol-3-ium nitrate

The title salt, C9H11N2 (+)·NO3 (-), features a planar cation (r.m.s. for 11 non-H atoms = 0.016 Å). In the crystal, N-H⋯O hydrogen bonds link nitrate and benzimidazole ions into a three-dimensional network.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s160053681004568x